Chapters 1-2

Question Answer
Rules for naming acids with oxygen 1. anion ends in -ate, suffix -ic acid. 2. anion ends in -ite, suffix = -ous acid
Rules for naming acids without oxygen Anion ends in -ide: Hydro-root-ic acid
Acids certain molecules that contain free H+ ions. One of more H+ attatched to an anion
Name the prefixes for naming nonmetalic binary compounds mono, di, tri, tetra, penta, hexa, hepta, octa, nona, deca
Naming binary covalent compounds: 2 nonmetals 1. first element in formula named first. 2. 2nd element named as anion (-ide) 3. prefixes denote numbers of atoms present. 4. mono never used for naming first element
Naming oxyanions Smallest number = Hypo-root-ite. Small number = root-ite. Large number = root-ate. Largest number = Per-root-ate.
Oxyanions series of anions that contain atoms of given element and different numbers of O atoms
Naming binary compounds: Metals sometimes form more than 1 type of cation. Charge on metal ion must be specified by roman numeral. Elements that only form 1 cation don't need roman numerals. Expections: Ag+ always the same and Zn+2 always the same.
To name binary compounds, + monoatomic cation, - monoatmic anion 1. cation always named first. 2. monoatomic cation takes name from name of element. 3. monoatomic anion root + -ide
periods horizontal row of elements
noble gases group 8A, monoatomic gases, little chemical reactivity
Halogens Group 7A, diatomic molecules, ions charge 1-
alkaline earth metals Group 2A, 2+ charged ions
alkali metals group 1A, active elements that form ions with +1 charge
groups/families vertical columns, similar chemical properties
nonmetals upper right corner of table. Tend to gain electrons. lack physical properties of metals. form negative ions. bond to each other with covalent bonds
metals efficient conductors of heat and electricity. malleable (into thin sheets). ductile (into wires). lustrous appearance. majority of elements.
periodic table shows all known elements, gives information about each. letters in boxes = symbols for the elements
polyatomic ions many atom ions, can be in ionic compounds
ionic solid solid consisting of oppositely charged ions
ionic bonding force of attraction between oppositely charged ions. cation and anion.
anion ion with negative charge, takes electron
cation one electron stripped off. positive ion.
ion atom or group of atoms that has a net positive or negative charge
space-filling model relative sizes of atoms as well as relative orientations in molecule
structural formula individual bonds shown, may not indicate actual shape of molecule. line = individual bonds. to show shape: dotted lines behind plane of paper, wedges in front of plane of paper
chemical formula symbols for elements to indicate types of atoms present. subscripts = number of atoms.
molecules held together by covalent bonds. move around as independent units.
covalent bonds sharing electrons
chemical bonds hold together atoms in a compound
mass number number of protons + neutrons, in superscript
Atomic number number of protons, in subscript
Isotopes Atoms with the same number of protons, but different numbers of neutrons. Almost exactly the same properties.
Neutrons Same mass at p+, but not charge.
Protons Positive charge = electon's negative charge
Modern atom model Tiny nucleus with electrons moving about. Chemistry of atom results from electrons. Nucleus made of P+ and N0. Number and arrangement of e- accounts for chemical properties.
Nuclear atom Rutherford. Center = positive charge (Nucleus) with electrons moving arorund nucleus at large distance relative to nuclear radius
Gold foil experiment Tests Thomson's plum pudding model. Directs alpha particles at thin sheet of gold foil. Alpha particles should crash right though foil with minor deflects. Many particles deflected at large angles, some reflected, majority go through. Huge surprise. Plum pudding model could not be correct. Results could only have been caused by center of concentrated positive charge that contains most of atom's mass. Deflected particles = "close encounters" with nucleus
Ernest Rutherford Gold foil test, nuclear atom
3 types of radioactive emissions Gamma (high energy light), Beta (High speed electron), Alpha (2+ charge, helium nucleus)
Radioactivity Spontaneous emission of radiation.
Plum Pudding model JJ Thompson. After doing cathode-ray experiment with various types of metals, hypothesized that all atoms have electrons. Atoms neutral, therefore also had to have some positive charge. Atom = Diffuse cloud of positive charge with negative electrons imbedded in it.
Cathode-ray tube experiment Partially evacuated tube. High voltage through tube, a 'ray' or cathode ray produced. Produced at - electrode, repelled by negative pole of magnet. Thought ray was negatively charged particles called electrons. Develops charge-to-mass ratio of electron. e/m = -1.76 x 10^8 C/g
JJ Thompson Discovers electrons, plum pudding model
Avogardo's Hypothesis At the same temperature and pressure, equal volumes of different gases contain the same number of particles. Volume of a gas determined by number of particles present.
Dalton's atomic theory. 1. Each element is made up of tiny particles called atoms. 2. Atoms of a given element are identical. Atoms of different elements are different in some fundamental way or ways. 3. Chemical compounds are formed when atoms of different elements combine with each other. compounds always the same relative numbers and types of atoms. 4. Chemical reactions involve reorganization of atoms. Changes the way they are bound together. Atoms themselves are not changed.
Law of multiple proportions If elements composed of tiny individual particles, given compound always the same combination of these atoms. Why same relative masses of elements were always found in a given compound. When two elements form a serries of compounds, the ratios of the first masses of the second element that combine with 1 gram of the first element can always be reduced to small whole numbers. Leads to hypothesis that each element consisted of certain type of atom and compounds were formed by specific combinations of these atoms.
John Dalton Law of multiple proportions, atomic theory, atomic masses
Law of Definite Proportions A given compound always contains exactly the same proportion of elements by mass.
Phlogiston Stahl thought it flowed out of burning material. Things stop burning because container filled up with phlogiston. Discovered phlogiston actually oxygen.
Robert Boyle First "chemist." Relationship between pressure and volume. End of Greek 4 system. ideas about chemical elements
Greeks believed matter composed of Fire, earth, air, water
Fahrenheit to Celsius TF = TC x 9F/5C + 32F
Elements Substances that cannot be decomposed into simple substances by physical or chemical means. Composed of atoms with nuclei and electrons.
Chemical change Given substance becomes new substance or substances with different properties and different composition
Compound Substance with constant composition. Can be broken down into elements by chemical processes
Paper chromatography porous paper and drop of mixture
Chromatography Mobile phase, either gas or liquid. Stationary phase, solid. Components with high affiinity for mobile phase move quickly thorugh chromatographic system
Filtration Solid and liquid. Put through mesh paper, liquid leaves solid behind
Distillation Depends on volatility (how readily substances become gases). Boil through cool tube into flask. Sometimes required multi-step distillation
physical changes eg. boiling/freezing
pure substance one with constant composition
solution homogeneous mixture
Heterogeneous mixture visibly distinguishable parts, can be usually separated into 2 or more homogeneous parts
Homogeneous mixture visiblely indistinguishable parts
Gas No fixed volume or shape, compressible
Liquid Definite volume, no specific shape
Solid rigid, fixed volume and shape
Density mass/volume
Converting Temperature (Kelvin) to Temperature (Celsius) T(K) = T(C) + 273.15
Unit factor Doesn't change value, only units
Dimensional analysis/unit factor method Convert a given result from one system of units to another
Sig fig calculations: Rounding Use only the first number to the right of the last sig fig, don't round until the end.
Sig fig calculations: Addition or subtraction Same number of decimal places as limiting term
Sig fig calculations: Multiply or divide Number of sig figs same as least precise measurement (limiting term)
Rules for counting sig figs: definitions yes, infinite sig figs
Rules for counting sig figs: counted numbers yes, infinite sig figs
Rules for counting sig figs: trailing zeros only with decimal point
Rules for counting sig figs: captive zeros yes
Rules for counting sig figs: leading zeros no
Rules for counting sig figs: nonzero integers yes
Systematic error AKA Determinate error. Either always high or low. If systematic error absent, precision indication of accuracy.
Random error AKA Indeterminate error. Equal probability of being high or low.
Precision Degree of agreement among several measurements of the same quantity. Reproductability.
Accuracy Agreement of particular value to true value
Significant Figures Uncertanty of last number
Uncertain digits Vary
Certain digits Remain the same regardless of who makes the measurements
Weight Force g exerts on an object to measure mass. Varies with gravity.
Mass Resistance of an object to change
SI System System Internationale. Prefixes change size.
Natural Law vs. Theory Natural Law: Summy of observed (measurable) behavior. Theory: Attempt to explain WHY it happened.
Natural law See that same observation applies to many different system. Generalized. Eg. Law of Conservation of Mass
What is a theory, or a model Created by many tested hypotheses. Interpretation for why an observation my have occured. Subject to change. Future predictions can lead to experiments which can lead to a modified theory. An educated guess.
quantitative observations numbers and units, measurements
Qualitative observations no numbers
Hypothesis Possible explanation
What is the scientific method? 1. Collect data (observations) 2. Formulate hypothesis (suggest possible explanations) 3. Test hypothesis (do experiments)
Microscopic world World we cannot see
Macroscopic world World we can see
What is a scanning tunnel microscope (STM) Uses e- current to see very small objects
Described why the cooled melted wax had a hole in the middle. Hardened from the outside in, as outside hardens, volume of inside decreased, and therefore density increased and it sank to the bottom
What is the densest element? Osnium
What is rheoscopic fluid? Shows dynamics, tests pressures, made up of different densities
Describe centrifugation Rheoscopid fluid spins around in centrifuge, denser things go to the bottom, sepparates based on density
Describe the wax density demo Solid wax sinks in liquid wax -- more dense
femto (f) 10^-15
pico (p) 10^-12
nano (n) 10^-9
micro (ยต) 10^-6
milli (m) .001
centi (c) .01
deci (d) .1
deca (dk) 10
hecta (h) 100
kilo (k) 1000
mega (M) 10^6
giga (g) 10^9
tera (t) 10^12
What happened in the stoplight reaction? Orangish yellowish liquid, shaken, turns amber red, goes quickly back to orange. Shake up and own, from orange to green, to blackish purple.
120 cards - created sep 13, 4:36pm

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