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Practice Test
: Chapter 6
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How do you solve a Hess's Law problem
constant volume
kinetic energy
first law of thermodynamics
What does the sign of ∆H indicate?
energy (as heat) released by reaction
calorimeter
Direction of heat flow at constant pressure.
=c x m x ∆T
The energy of the universe is constant. Same as law of conservation of energy
No work is done. Energy change determined by measuring increase in the temperature of water and other calorimeter parts. ∆E = q +w = qv
Device used experimentally t determine the heat associated with a chemical reaction
Several reactions to be manipulated and combined to finally give the reaction of interest. Work backward from the required reaction. Reverse any reactions as needed to give either required reactants and products. Multiply reactions to give the correct numbers of reactants and products
energy due to motion of the object. Depends on the mass of the object m and velocity v. KE = 1/2 mv^2
Short Answer
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work
law of conservation of energy
2 characteristics of ∆H for a reaction
Standard Enthalpy of Formation ∆Hf˚
frictional heating
Multiple Choice
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hess's law
Energy flows out of a system. Some of the potential energy stored in the chemical bonds is being converted to thermal energy via heat. ∆(PE) transferred to surroundings through heat
Transfer of energy between two objects due to a temperature difference. Not a substance contained by an object
H products - H reactants. Endothermic: ∆H = +. Exothermic: ∆H = -
energy due to position or composition
Change in enthalpy in going from some initial state to some final state is independent of the pathway. In going from a particular set of reactants to a particular set of products, the change in enthalpy is the same whether the reaction takes place in one step or in a series of steps. ∆H = enthalpy change
∆H =
=c x m x ∆T
Change in enthalpy that accompanies the formation of one mole of a compound from its elements with all substances in their standard states
Kinetic energy transferred to a surface as heat
Energy can be converted from one form to another but can be neither created nor destroyed
H products - H reactants. Endothermic: ∆H = +. Exothermic: ∆H = -
exothermic
Transfer of energy between two objects due to a temperature difference. Not a substance contained by an object
No work is done. Energy change determined by measuring increase in the temperature of water and other calorimeter parts. ∆E = q +w = qv
Energy flows out of a system. Some of the potential energy stored in the chemical bonds is being converted to thermal energy via heat. ∆(PE) transferred to surroundings through heat
A change in function in going from one state to another state is independent of particular pathway taken between two states. Eg. Total energy. Work and heat are not state functions
Heat capacity per mole
specific heat capacity
Heat capacity per mole
Energy can be converted from one form to another but can be neither created nor destroyed
heat capacity per gram
The energy of the universe is constant. Same as law of conservation of energy
If a reaction is reversed, the sign of ∆H is also reversed. The magnitude of ∆H is directly proportional to the quantities of reactants and products in a reaction. If the coefficients in a balanced reaction are multiplied by an integer, the value of ∆H is multiplied by the same integer
heat
Transfer of energy between two objects due to a temperature difference. Not a substance contained by an object
H = E + PV. State function. At constant pressure, (where only PV work is allowed), the change in enthalpy ∆H of the system is equal to the energy flow as heat. Heat of reaction = change in enthalpy
Subtracting the enthalpies of formation of the reactants from the enthalpies of formation of the products. Multiply the enthalpies of formation by integers as required by the balanced equation. When reaction reversed, sign changes ∆H. Elements in their standard states are not included
Heat capacity per mole
True or False
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constant pressure calorimetry
Corresponding process has been carried out under standard conditions
True
False
temperature
A change in function in going from one state to another state is independent of particular pathway taken between two states. Eg. Total energy. Work and heat are not state functions
True
False
w = -P∆V
Science of measuring heat based on observing temperature change
True
False
potential energy
energy due to position or composition
True
False
Degree symbol on a thermodynamic function
Kinetic energy transferred to a surface as heat
True
False
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